Fullerenes
- Fullerenes are considered
as the third allotropic form of carbon (along with graphite and
diamond) They are made of only carbon atoms resembling a cage
like structure or like a soccer ball.
- In some soccer balls there are geometrical shapes of hexagons and
pentagons, a typical fullerene has carbon atoms at the corners of these
shapes.
- The widely known fullerene is C60. Sixty carbon atoms are present
at the corners of 20 hexagons and ten pentagons on the surface of the
spherical shaped structure referred to as “Bucky ball”.
- Along with C60, C70 and a few others were discovered in 1985.
- Its first practical synthesis was achieved in 1990.
Discovery
Graphite is subjected to high energy pulsed laser beam
and the product was observed to have peaks of high intensity at m=720
and 840 in the mass spectrum corresponding to C60 and C70.
Nomenclature
Fullerenes and Buckminster fullerene are so called in honour of Buckminster
Fuller an architect/Engineer who used to design and construct the geodesic
domes resembling them
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