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Esters

esters

  • An ester is a condensation product of an acid and an alcohol.
  • The formation of an ester from an acid and an alcohol is termed esterification.
  • During esterification a molecule of water is eliminated.
  • The formation of an ester from the acid and alcohol requires the use of heat and a dehydrating agent like conc. sulfuric acid. (Is there a difference between a dehydrating agent and a drying agent?)
  • Most esters are pleasant smelling compounds and are useful as constituents of perfumes, cosmetics and food flavouring agents.
  • Many esters are of medicinal importance.
  • Methylsalicylate is a constituent of many ointments like Vicks, Amrutanjan, Tiger Balm, Bengay and so on. (It is a muscle relaxant). Here is a list of some esters, their odours, the acid and alcohol from which they are derived.
Acid Alcohol Ester Smell
Acetic acid Benzyl alcohol Benzyl acetate Jasmine
Butyric acid Methyl alcohol Methyl butyrate Apple
Butyric acid Ethyl alcohol Ethyl butyrate Pineapple
Acetic acid Isoamyl alcohol Isoamyl acetate banana
Anthranilic acid Methyl alcohol Methyl anthranilate grapes
Salicylic acid Methyl alcohol Methyl salicylate oil of wintergreen (Vicks)